Free PDF The Role of the Solvent in Chemical Reactions (Oxford Chemistry Masters)
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The role of the solvent in chemical reactions is one of immediate and daily concern to the practising chemist. Whether in the laboratory, or in industry, most reactions are carried out in the liquid phase. In the majority of these, one or two reacting components, or reagents, are dissolved in a suitable medium and the reaction is allowed to take place. Given the importance of solvent, the need for an in-depth understanding of this topic is obvious. However, many inorganic and organic chemistry texts only make passing references to solvents, or worse still, fail to mention that a given reaction takes place in a particular solvent at all. This book successfully addresses the gap in our understanding of solvent chemistry, and brings the role of the solvent rightly to the fore.The book begins with a summary of essential thermodynamic and kinetic facts, emphasizing aspects of these fields, where relevant, to reactions in solution. Chapter 2 introduces the reader to the role of the solvent purely as a medium, touching on early theories based on electrostatic considerations (Born and Kirkwood-Onsager) and the solubility parameter (Hildebrand). Chapter 3 discusses the role of solvent as an active participant, chiefly through hydrogen bonding, Brnsted-Lowry and Lewis acid-base interactions, including hard and soft acids and bases. The ability of solvents to serve as media for oxidation and reduction is also touched upon. There then follows a chapter on chemometrics; the application of statistical methods to chemical phenomena and spectra, chiefly linear free energy correlations and principal component analysis. A novel method for the presentation of data is also described. In chapter 5, methods of theoretical calculation are discussed. These include quantum-mechanical ab-initio and semiempirical methods, integral-equation theories, and methods based on statistical mechanics (Monte Carlo and molecular dynamics). Examples to illustrate these methods are detailed in the chapter. Chapters 6 and 7 look at a selection of particular classes of solvents including aprotic-dipolar, acidic, basic, room-temperature ionic, and chiral. The suitability of examples from each class of solvent for particular purposes is also discussed. The final chapter presents some concluding observations. Throughout the book, the authors use a semiquantitative and thermodynamically based approach, deliberately avoiding unnecessary detail or rigour, so that the discussions are accessible to both senior undergraduates and postgraduates. The text is also interspersed with helpful examples taken from both inorganic and organic chemistry. People University of Bath Core staff Director Professor Matthew Davidson Matthew Davidson established the Centre for Sustainable Chemical Technologies at Bath in 2008 and is currently The Royal Society of Chemistry - our structure The Royal Society of Chemistry is constituted by Royal Charter We are a registered charity and regulated by the Charities Commission Bulk Heterojunction Solar Cells: Morphology and Ye Huang received her BS degree in polymer science from Sichuan University in 2007 and PhD degree in polymer physics and chemistry from the Institute of Chemistry Professor Behdad Moghtaderi / Staff Profile / The Professor Behdad Moghtaderi's research expertise is in the general field of energy and the environment He has broad experience knowledge and achievements in this Articles - Ineos INEOS appeals to jeremy corbyn as labour leader pledges to ban fracking FRACKING for shale gas in Britain will be banned if the Labour Party wins the next UK General Syllabus - University of Madras 1967 Genetics Oxford IBH Publications Physico-chemical nature of fresh Electron transport chain - components and reactions of ETC Role of Total Citations - European Journal of Chemistry European Journal of Chemistry Popular Articles 14-Diazabicyclo[222]octane (DABCO) as a useful catalyst in organic synthesis Essay Writing Service - EssayEruditecom We provide excellent essay writing service 24/7 Enjoy proficient essay writing and custom writing services provided by professional academic writers Eurasc - New Members - eurascorg Professor Tomas Torres Organic Chemistry at the Autonoma University of Madrid (Spain) Toms Torres is Director of the Institute for Advanced Research in Chemical Metalloid - Wikipedia A metalloid is any chemical element which has properties in between those of metals and nonmetals or that has a mixture of them There is neither a standard
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